Pregunta 6 · Complements de química URV Examen Primer Parcial. Complements de Química
Tema: Enlace covalente: Lewis, VSEPR e hibridación · Del examen Examen Primer Parcial. Complements de Química
Enunciado
Pregunta 6. Hybridization and geometry of functional groups
Consider the bifunctional organic molecule shown below:
a)
Identify the hybridization and molecular geometry around the methyl carbon marked as A.
b)
Describe the nature and orbital overlap of the carbon-carbon single bond indicated by B.
c)
Determine the hybridization of the nitrile nitrogen atom marked as C.
d)
What is the bond angle at the nitrile carbon atom marked as D ?
e)
Indicate the hybridization of all non-hydrogen atoms in the structure:

Solución
Según los criterios oficiales de corrección
a) Hybridization of methyl carbon marked as A
Solución:
a) Molecular geometry around the methyl carbon marked as A
Solución: tetrahedral / tetraédrica
b) Nature and orbital overlap of the carbon-carbon single bond indicated by B
Solución:
c) Hybridization of the nitrile nitrogen atom marked as C
Solución:
d) Bond angle at the nitrile carbon atom marked as D
Solución:
e) Hybridization of alkyl chain methylene carbons (-CH2-CH2-)
Solución:
e) Hybridization of ester carbonyl carbon
Solución:
e) Hybridization of carbonyl oxygen (=O)
Solución:
e) Hybridization of ester ether oxygen (-O-)
Solución:
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